Ida Nielsen

I graduated from the University of Copenhagen, Denmark in June 2021 with a MSc in Chemistry with inorganic specialization. For my graduate thesis, I worked on nanoparticle synthesis, especially ion exchange of Cu2-xS nanoparticles to form CuInS2 nanoparticles, and with powder X-ray diffraction and Pair Distribution Function analysis studied their structure and how different synthesis parameters influence the structure of these materials.

My project with SwedNess is focused on unravelling the role that water plays in both stabilizing the structure and facilitating fast ion transport in Prussian Blue Analogues (PBAs) battery materials. To study these materials a range of techniques will be used; especially X-ray and neutron diffraction to determine accurate structures of PBAs and the position of water within the structure, and neutron spectroscopy to probe the dynamics involved in ion transport and phase transitions. Neutrons are essential to study these materials as the X-ray scattering lengths of water and sodium are approximately equal. Moreover, operando diffraction techniques will be used to monitor the structural changes during electrochemical cycling. This work is both targeted at developing a fundamental understanding of PBAs as well as understanding properties which will lead to improved energy storage materials.

University: Uppsala University
Thesis Title: Water in Prussian blue analogues: A blessing or a curse?

Publications

Local structure of hydrated and dehydrated Prussian white cathode materials, Ida Nielsen, M. Eremenko, Y. Zhang, M.G. Tucker, Journal of Materials Chemistry C (2025) DOI: 10.1039/D5TC03143E

Unravelling the origin of capacity fade in Prussian white hard carbon full cells through operando X-ray diffraction, Ida Nielsen, C. A. Hall, A-M. Mattsson, R. Younesi, A. Buckel, G. Ek, and W. R. Brant. J. Mater. Chem. A. 2024, 12, 17413-17421. https://doi.org/10.1039/D4TA02325K

Ion-intercalation mechanism and structural relaxation in layered iron phosphate Na3Fe3(PO4)4 cathodes, C. L. Jakobsen, M. Johansen, T. Ericsson, L. Häggström, C. K. Christensen, Ida Nielsen, W. R. Brant, and D. B. Ravnsbæk. Front. Batter. Electrochem. 2024, 3, 1433241. https://doi.org/10.3389/fbael.2024.1433241

Study of degradation mechanisms in aqueous-processed Ni-rich cathodes for enhanced sustainability of batteries, H. Chen, A-M. Mattsson, L. King, H. Liu, Ida Nielsen, T. Ericson, A. Preobrajenski, W. R. Brant, and M. Hahlin. J. Mater. Chem. A. 2024, 12, 25393-25406. https://doi.org/10.1039/D4TA03592E

Impact of sodium on the water dynamics in Prussian blue analogues, Ida Nielsen, A. Ulander, F. Juranyi, S. R. Larsen, M. Karlsson, W. R. Brant, and M. S. Andersson. Chem. Mater. 2024, 36, 11246-11253. https://doi.org/10.1021/acs.chemmater.4c02326

Determining internal porosity in Prussian blue analogue cathode materials using positron annihilation lifetime spectroscopy. D. Boras, I. Nielsen, A. Buckel, T. Ericsson, L. Häggström, R. Younesi, T. Stabb, W.R. Brant. Journal of Material Science; Vol. 58. (2023) https://link.springer.com/article/10.1007/s10853-023-09025-x

Water driven phase transitions in Prussian white cathode materials, I. Nielsen, D. Dzodan, D.O. Ojwang, P.F. Henry, A. Ulander, G. Ek, L. Häggström, T. Ericsson, H.L.B. Boström, W.R. Brant. Journal of Physics: Energy, Vol. 4, nr 4. (2022) https://iopscience.iop.org/article/10.1088/2515-7655/ac9808